Here's how it's done:
5-6 large navel oranges
4 1/2 c granulated sugar
1 1/2 c water
Score each orange thru the pith about 6 times around. Remove from the orange and with a sharp paring knife remove the excess pith. It's okay to leave some on but you don't want it to be too thick. This is the bitter part. After you have done this with all your oranges, cut the peel into 1/4" slices and place into a large sauce pan. Add enough cold water to cover and bring to a boil. Once it has come to a full boil, pour off the water and start again with fresh cold water. You want to repeat this process 3-4 times in order to soften up the peel and lessen their bitterness.
Add 1 1/2 c water and 4 1/2 c sugar to a heavy sauce pan. Bring to a simmer and continue cooking until the temperature on a candy thermometer reads 300* - 340* (thin thread stage). At this time, add the orange peel and adjust the heat to keep the peel simmering for about 45 minutes or until translucent. Do not stir during this time.
Have a bowl with about 1 1/2 c sugar ready. Once the peel has finished simmering, drain off the syrup (you can reserve this and use for other recipes or beverages if you desire). Dump the peel into the bowl of sugar and toss to coat. Remove to a wire rack and dry for several hours or overnight.
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